Geostandards and Geoanalytical Research Bibliographic Review 2010     

Klaus Peter Jochum  Xiaohong Wang  Uwe Nohl  Steffen Schmidt  Beate Schwager  Brigitte Stoll  Qichao Yang  Ulrike Weis 《Geostandards and Geoanalytical Research》2011,35(4):485-488

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Non‐Matrix‐Matched Calibration for the Multi‐Element Analysis of Geological and Environmental Samples Using 200 nm Femtosecond LA‐ICP‐MS: A Comparison with Nanosecond Lasers     

Klaus Peter Jochum  Brigitte Stoll  Ulrike Weis  Dorrit E. Jacob  Regina Mertz‐Kraus  Meinrat O. Andreae 《Geostandards and Geoanalytical Research》2014,38(3):265-292

LA‐ICP‐MS is one of the most promising techniques for in situ analysis of geological and environmental samples. However, there are some limitations with respect to measurement accuracy, in particular for volatile and siderophile/chalcophile elements, when using non‐matrix‐matched calibration. We therefore investigated matrix‐related effects with a new 200 nm femtosecond (fs) laser ablation system (NWRFemto200) using reference materials with different matrices and spot sizes from 10 to 55 μm. We also performed similar experiments with two nanosecond (ns) lasers, a 193 nm excimer (ESI NWR 193) and a 213 nm Nd:YAG (NWR UP‐213) laser. The ion intensity of the 200 nm fs laser ablation was much lower than that of the 213 nm Nd:YAG laser, because the ablation rate was a factor of about 30 lower. Our experiments did not show significant matrix dependency with the 200 nm fs laser. Therefore, a non‐matrix‐matched calibration for the multi‐element analysis of quite different matrices could be performed. This is demonstrated with analytical results from twenty‐two international synthetic silicate glass, geological glass, mineral, phosphate and carbonate reference materials. Calibration was performed with the certified NIST SRM 610 glass, exclusively. Within overall analytical uncertainties, the 200 nm fs LA‐ICP‐MS data agreed with available reference values.  相似文献   

Geostandards and Geoanalytical Research Bibliographic Review 2013     

Klaus Peter Jochum  Uwe Nohl  Beate Schwager  Brigitte Stoll  Philip Suesser  Ulrike Weis 《Geostandards and Geoanalytical Research》2014,38(4):513-515

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The ground calibration setup of OMEGA and VIRTIS experiments: description and performances     

Guillaume Bonello  Jean Pierre Bibring  Alain Soufflot  Yves Langevin  Brigitte Gondet  Michel Berthé  Charles Carabetian 《Planetary and Space Science》2005,53(7):711-728

Hyperspectral imagery is an essential technique for remote sensing of surfaces and atmospheres of planetary objects. However, given the instrumental complexity of coupling imaging and spectroscopy, in particular in the infrared, an in-depth ground calibration is mandatory to enable an unbiased and optimized data reduction.This paper presents the ground calibration setup designed and implemented for the visible and near infrared imaging spectrometers VIRTIS/ROSETTA, and OMEGA/MARS-EXPRESS, and summarizes the main results obtained in validating the required performances.  相似文献   

MediaPark Köln,Germany — Urban planning vision becomes reality     

Utz Ingo Küpper Dr.  Brigitte Göttgens 《GeoJournal》1991,25(4):443-446

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Evaporation and recondensation of sodium in Semarkona Type II chondrules     

Roger H. Hewins  Brigitte Zanda  Claire Bendersky 《Geochimica et cosmochimica acta》2012

We have investigated the Na distributions in Semarkona Type II chondrules by electron microprobe, analyzing olivine and melt inclusions in it, mesostasis and bulk chondrule, to see whether they indicate interactions with an ambient gas during chondrule formation. Sodium concentrations of bulk chondrule liquids, melt inclusions and mesostases can be explained to a first approximation by fractional crystallization of olivine ± pyroxene. The most primitive olivine cores in each chondrule are mostly between Fa₈ and Fa₁₃, with 0.0022–0.0069 ± 0.0013 wt.% Na₂O. Type IIA chondrule olivines have consistently higher Na contents than olivines in Type IIAB chondrules. We used the dependence of olivine–liquid Na partitioning on FeO in olivine as a measure of equilibration. Extreme olivine rim compositions are ～Fa₃₅ and 0.03 wt.% Na₂O and are close to being in equilibrium with the mesostasis glass. Olivine cores compared with the bulk chondrule compositions, particularly in IIA chondrules, show very high apparent D_Na, indicating disequilibrium and suggesting that chondrule initial melts were more Na-rich than present chondrule bulk compositions. The apparent D_Na values correlate with the Na concentrations of the olivine, but not with concentrations in the bulk melt. We use equilibrium D_Na to find the Na content of the true parent liquid and estimate that Type IIA chondrules lost more than half their Na and recondensation was incomplete, whereas Type IIAB chondrules recovered most of theirs in their mesostases.Glass inclusions in olivine have lower Na than expected from fractionation of bulk composition liquids, and mesostases have higher Na than expected in calculated daughter liquids formed by fractional crystallization alone. These observations also require open system behavior of chondrules, specifically evaporation of Na before formation of melt inclusions followed by recondensation of Na in mesostases. Within this record of evaporation followed by recondensation, there is no indication of a stage with zero Na in the chondrules, which is predicted by models for shock wave cooling at canonical nebular pressures, suggesting high P_T.The high Na concentrations in olivine and mesostases indicate very high P_Na while chondrules were molten. This may be explained by local, very high particle densities where Type II chondrules formed. The high P_T, P_Na and number densities of chondrules implied suggest formation in debris clouds after protoplanetary collisions as an alternative to formation after passage of shock waves through large particle-rich clumps in the disk. Encounters of partially molten chondrules should have been frequent in these dense swarms. However, in many ordinary chondrites like Semarkona, “cluster chondrites”, compound chondrules are not abundant but instead chondrules aggregated into clusters. Chondrule melting, cooling and clustering in dense swarms contributed to rapid accretion, possibly after collision, by fallback on the grandparent body and by reaccretion as a new body downrange.  相似文献   

Eemian landscape response to climatic shifts and evidence for northerly Neanderthal occupation at a palaeolake margin in northern Germany     

Michael Hein  Brigitte Urban  David Colin Tanner  Anton Hermann Buness  Mario Tucci  Philipp Hoelzmann  Sabine Dietel  Marie Kaniecki  Jonathan Schultz  Thomas Kasper  Hans von Suchodoletz  Antje Schwalb  Marcel Weiss  Tobias Lauer 《地球表面变化过程与地形》2021,46(14):2884-2901

The prevailing view suggests that the Eemian interglacial on the European Plain was characterized by largely negligible geomorphic activity beyond the coastal areas. However, systematic geomorphological studies are sparse. Here we present a detailed reconstruction of Eemian to Early Weichselian landscape evolution in the vicinity of a small fingerlake on the northern margin of the Salzwedel Palaeolake in Lower Saxony (Germany). We apply a combination of seismics, sediment coring, pollen analysis and luminescence dating on a complex sequence of colluvial, paludal and lacustrine sediments. Results suggest two pronounced phases of geomorphic activity, directly before the onset and at the end of the Eemian period, with an intermediate period of pronounced landscape stability. The dynamic phases were largely driven by incomplete vegetation cover, but likely accentuated by fluvial incision in the neighbouring Elbe Valley. Furthermore, we discovered Neanderthal occupation at the lakeshore during Eemian pollen zone (PZ) E IV, which is chronologically in line with other known Eemian sites of central Europe. Our highly-resolved spatio-temporal data substantially contribute to the understanding of climate-induced geomorphic processes throughout and directly after the last interglacial period. It helps unraveling the landscape dynamics between the coastal areas to the north and the loess belt to the south.  相似文献   

Homogeneous distribution of Fe isotopes in the early solar nebula     

Kun Wang  Frédéric Moynier  Jean‐Alix Barrat  Brigitte Zanda  Randal C. Paniello  Paul S. Savage 《Meteoritics & planetary science》2013,48(3):354-364

To examine the iron (Fe) isotopic heterogeneities of CI and ordinary chondrites, we have analyzed several large chips (approximately 1 g) from three CI chondrites and three ordinary chondrites (LL5, L5, and H5). The Fe isotope compositions of five different samples of Orgueil, one from Ivuna and one from Alais (CI chondrites), are highly homogeneous. This new dataset provides a δ⁵⁶Fe average of 0.02 ± 0.04‰ (2SE, n = 7), which represents the best available value for the Fe isotopic composition of CI chondrites and probably the best estimate of the bulk solar system. We conclude that the homogeneity of CI chondrites reflects the initial Fe isotopic homogeneity of the well‐mixed solar nebula. In contrast, larger (up to 0.26‰ in δ⁵⁶Fe) isotopic variations have been found between separate approximately 1 g pieces of the same ordinary chondrite sample. The Fe isotope heterogeneities in ordinary chondrites appear to be controlled by the abundances of chondritic components, specifically chondrules, whose Fe isotope compositions have been fractionated by evaporation and recondensation during multiple heating events.  相似文献   

Raman spectroscopic properties and Raman identification of CaS‐MgS‐MnS‐FeS‐Cr2FeS4 sulfides in meteorites and reduced sulfur‐rich systems     

Caroline Avril  Valérie Malavergne  Razvan Caracas  Brigitte Zanda  Bruno Reynard  Emeline Charon  Ema Bobocioiu  Fabrice Brunet  Stephan Borensztajn  Sylvain Pont  Martine Tarrida  François Guyot 《Meteoritics & planetary science》2013,48(8):1415-1426

Raman spectra were acquired on a series of natural and synthetic sulfide minerals, commonly found in enstatite meteorites: oldhamite (CaS), niningerite or keilite ((Mg,Fe)S), alabandite (MnS), troilite (FeS), and daubreelite (Cr₂FeS₄). Natural samples come from three enstatite chondrites, three aubrites, and one anomalous ungrouped enstatite meteorite. Synthetic samples range from pure endmembers (CaS, FeS, MgS) to complex solid solutions (Fe, Mg, Ca)S. The main Raman peaks are localized at 225, 285, 360, and 470 cm^?1 for the Mg‐rich sulfides; at 185, 205, and 285 cm^?1 for the Ca‐rich sulfides; at 250, 370, and 580 cm^?1 for the Mn‐rich sulfides; at 255, 290, and 365 cm^?1 for the Cr‐rich sulfides; and at 290 and 335 cm^?1 for troilite with, occasionally, an extra peak at 240 cm^?1. A peak at 160 cm^?1 is present in all Raman spectra and cannot be used to discriminate between the different sulfide compositions. According to group theory, none of the cubic monosulfides oldhamite, niningerite, or alabandite should present first‐order Raman spectra because of their ideal rocksalt structure. The occurrence of broad Raman peaks is tentatively explained by local breaking of symmetry rules. Measurements compare well with the infrared frequencies calculated from first‐principles calculations. Raman spectra arise from activation of certain vibrational modes due to clustering in the solid solutions or to coupling with electronic transitions in semiconductor sulfides.  相似文献   

The significance of cryoturbation phenomena in environmental reconstruction     

Brigitte Van Vliet-Lanoë 《第四纪科学杂志》1988,3(1):85-96

Cryoturbation results mainly from differential heave related to (1) drainage and thermal conditions and (2) frost susceptibility. Loadcasting and cryostatic pressures are restricted to wet soils such as pure silt or silty sand. The translocation of fine particles resulting from repeated freezing and thawing can promote frost susceptibility in a previously non-susceptible material, as well as a loss in stability of the surface horizons (liquefaction). Small and metric scale cryoturbations can be explained by this process. Large scale deformations and injections may be related to abnormal liquefaction not necessarily associated with frost. Regular patterns are associated with fissure nets. Upturned injections in a downslope direction attest to cryoturbation and frost creep. A lowering of the water table promotes the formation of drop-like cryoturbations, most of which can be related to seasonal frost in imperfectly to poorly drained soils. They are not indicative of permafrost except in well drained situations or in the case of flat bottomed involutions.  相似文献